Unravelling the ultrafast photodecomposition mechanism of dibenzoyl peroxide in solution by time-resolved IR spectroscopy

www.rsc.org | Jan 31, 2008

The photodecomposition of dibenzoyl peroxide leads to a benzoyloxy/phenyl radical pair plus CO2via concerted two-bond cleavage.

http://www.rsc.org/publishing/journals/CP/article.asp?doi=b718501d

Unravelling the ultrafast photodecomposition mechanism of dibenzoyl peroxide in solution by time-resolved IR spectroscopy

xlink.rsc.org | Jan 31, 2008

The ultrafast photo-fragmentation of dibenzoyl peroxide (DBPO) is studied using femtosecond UV excitation at 266 nm and mid-infrared broadband probe pulses to elucidate the dissociation mechanism.

http://xlink.rsc.org/?DOI=b718501d&RSS=1

Bibliography - Chemical Analysis and Property Studies

A number of calorimetric techniques have been applied to the study of polymeric materials. DSC techniques in particular have been used to evaluate thermal stability and to look for phase transitions (e.g. glass and liquid crystal transitions) associated with these materials.

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NMRanalyst Sample Application: 4-(2-Chloroacetyl)phenyl benzoate

Best 10 structures in decreasing rating (structure ID shown in parentheses): 1: 0.967598 ( 6927853) 2: 0.967245 ( 6989733) 3: 0.965006 ( 9184970) 4: 0.964835 (10564291) 5: 0.963305 ( U18) 6: 0.963208 (10016206) 7: 0.960537 (11807907) 8: 0.959723 ( 3660437) 9: 0.958883 (10540319) 10: 0.

http://www.sciencesoft.net/C15H11ClO3/index.html

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